Witbank Vanadium Plant in Transvaal, South Africa

Witbank Vanadium Plant in Transvaal, South Africa

South Africa Transvaal Bush Vader igneous about 2 billion t of vanadium and titanium magnetic iron ore. The main ore layer contains about 1.5% V 2 O 5 , 54% to 60% Fe and 12% to 14% TiO 2 .

Transvaal's Witbank Vanadium Plant

Its raw materials are as follows:

ingredient

Fe

V 2 O 5

TiO 2

Al 2 O 3

Cr 2 O 3

%

50~60

~2.5

8~20

1 to 9

~1.0

The production process is shown in Figure 1. The ore is ground to 70%-200 mesh, dehydrated, and added with soda ash, salt, and thenardite , oxidized and calcined at 1200 ° C in a rotary kiln. The discharged HCl gas is first sprayed with water, then neutralized with ammonia, and subjected to cyclic absorption, and NH 4 Cl reaches 150 to 180 g/L, and is used as a vanadium sinking agent. The calcined material has a large specific porosity and is leached by percolation with water. The leachate was subjected to precipitation of vanadium with NH 4 Cl to obtain ammonium metavanadate. Ammonium metavanadate was dried at 50 ° C and was white crystals and sold as a product. Further calcination and deamination to obtain red vanadium oxide as a catalyst. Further melting, can be made into a fuse sold, the ingredients are as follows:

ingredient

V 2 O 5

Na 2 O

SiO 2

Fe

As

P

S

Ammonium metavanadate /%

77.1

0.1

0.1

0.05

0.01

0.01

0.01

Red vanadium oxide foil /%

99.3

0.2

0.2

0.2

0.01

0.01

0.01

Figure 1 South Africa Witbank plant process

From ore to product, the total yield of vanadium is about 60%. After the vanadium-vanadium solution is evaporated and concentrated, NaCl can be precipitated, and the NH 4 Cl mother liquor can be returned to use.

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